Introductory Mathematics For Engineers – Lectures In Higher Mathematics by A D. Myškis

Prof. Myškis’ Lectures on Higher Mathematics is a textbook designed to cover key mathematical concepts for engineering students and technical colleges. It emphasises fundamental ideas and their practical applications in specialised fields, presented in an intuitive and accessible manner without unnecessary pedantry. The book focuses on building understanding through intuitive explanations of mathematical concepts and making their applications straightforward. It is intended for engineering students but is also suitable for home study and self-improvement.

The author, Prof. Anatoly Myškis, D.Sc., is well known not only for his original research but also for his equally original approach to the teaching of higher mathematics. He is one of the founders of the theory of differential equations with retarded argument.

His publications include Linear Differential Equations with Retarded Argument, Elements of Applied Mathematics (co-author), and Special Courses in Mathematics for Technical Colleges.

Translated from the Russian by V. M. Volosov, D. Sc.

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Contents

Chapter I. Variables and Functions
§ 1. Quantities

  1. Concept of a Quantity
  2. Dimensions of Quantities
  3. Constants and Variables
  4. Number Scale. Slide Rule
  5. Characteristics of Variables

§ 2. Approximate Values of Quantities
6. The Notion of an Approximate Value
7. Errors
8. Writing Approximate Numbers
9. Addition and Subtraction of Approximate Numbers
10. Multiplication and Division of Approximate Numbers. General Remarks

§ 3. Functions and Graphs
11. Functional Relation
12. Notation
13. Methods of Representing Functions
14. Graphs of Functions
15. The Domain of Definition of a Function
16. Characteristics of Behaviour of Functions
17. Algebraic Classification of Functions
18. Elementary Functions
19. Transforming Graphs
20. Implicit Functions
21. Inverse Functions

§ 4. Review of Basic Functions
22. Linear Function
23. Quadratic Function
24. Power Function
25. Linear-Fractional Function
26. Logarithmic Function
27. Exponential Function
28. Hyperbolic Functions
29. Trigonometric Functions
30. Empirical Formulas

Chapter II. Plane Analytic Geometry
§ 1. Plane Coordinates

  1. Cartesian Coordinates
  2. Some Simple Problems Concerning Cartesian Coordinates
  3. Polar Coordinates

§ 2. Curves in Plane
4. Equation of a Curve in Cartesian Coordinates
5. Equation of a Curve in Polar Coordinates
6. Parametric Representation of Curves and Functions
7. Algebraic Curves
8. Singular Cases

§ 3. First-Order and Second-Order Algebraic Curves
9. Curves of the First Order
10. Ellipse
11. Hyperbola
12. Relationship Between Ellipse, Hyperbola and Parabola
13. General Equation of a Curve of the Second Order

Chapter III. Limit. Continuity
§ 1. Infinitesimal and Infinitely Large Variables

  1. Infinitesimal Variables
  2. Properties of Infinitesimals
  3. Infinitely Large Variables

§ 2. Limits
4. Definition
5. Properties of Limits
6. Sum of a Numerical Series

§ 3. Comparison of Variables
7. Comparison of Infinitesimals
8. Properties of Equivalent Infinitesimals
9. Important Examples
10. Orders of Smallness
11. Comparison of Infinitely Large Variables

§ 4. Continuous and Discontinuous Functions
12. Definition of a Continuous Function
13. Points of Discontinuity
14. Properties of Continuous Functions
15. Some Applications

Chapter IV. Derivatives, Differentials, Investigation of the Behaviour of Functions
§ 1. Derivative

  1. Some Problems Leading to the Concept of a Derivative
  2. Definition of Derivative
  3. Geometrical Meaning of Derivative
  4. Basic Properties of Derivatives
  5. Derivatives of Basic Elementary Functions
  6. Determining Tangent in Polar Coordinates

§ 2. Differential
7. Physical Examples
8. Definition of Differential and Its Connection with Increment
9. Properties of Differential
10. Application of Differentials to Approximate Calculations

§ 3. Derivatives and Differentials of Higher Orders
11. Derivatives of Higher Orders
12. Higher-Order Differentials

§ 4. V. H.ospital’s Rule
13. Indeterminate Forms of the Type 0/0
14. Indeterminate Forms of the Type ∞/∞

§ 5. Taylor’s Formula and Series
15. Taylor’s Formula
16. Taylor’s Series

§ 6. Intervals of Monotonicity. Extremum
17. Sign of Derivative
18. Points of Extremum
19. The Greatest and the Least Values of a Function

§ 7. Constructing Graphs of Functions
20. Intervals of Convexity of a Graph and Points of Inflection
21. Asymptotes of a Graph
22. General Scheme for Investigating a Function and Constructing Its Graph

Chapter V. Approximating Roots of Equations. Interpolation
§ 1. Approximating Roots of Equations

  1. Introduction
  2. Cut-and-Try Method. Method of Chords. Method of Tangents
  3. Iterative Method
  4. Formula of Finite Increments
    5*. Small Parameter Method

§ 2. Interpolation
6. Lagrange’s Interpolation Formula
7. Finite Differences and Their Connection with Derivatives
8. Newton’s Interpolation Formulas
9. Numerical Differentiation

Chapter VI. Determinants and Systems of Linear Algebraic Equations
§ 1. Determinants

  1. Definition
  2. Properties
  3. Expanding a Determinant in Minors of Its Row or Column

§ 2. Systems of Linear Algebraic Equations
4. Basic Case
5. Numerical Solution
6. Singular Case

Chapter VII. Vectors
§ 1. Linear Operations on Vectors

  1. Scalar and Vector Quantities
  2. Addition of Vectors
  3. Zero Vector and Subtraction of Vectors
  4. Multiplying a Vector by a Scalar
  5. Linear Combination of Vectors

§ 2. Scalar Product of Vectors
6. Projection of Vector on Axis
7. Scalar Product
8. Properties of Scalar Product

§ 3. Cartesian Coordinates in Space
9. Cartesian Coordinates in Space
10. Some Simple Problems Concerning Cartesian Coordinates

§ 4. Vector Product of Vectors
11. Orientation of Surface and Vector of Area
12. Vector Product
13. Properties of Vector Product
14*. Pseudovectors

§ 5. Products of Three Vectors
15. Triple Scalar Product
16. Triple Vector Product

§ 6. Linear Spaces
17. Concept of Linear Space
18. Examples
19. Dimension of Linear Space
20. Concept of Euclidean Space
21. Orthogonality

§ 7. Vector Functions of Scalar Argument. Curvature
22. Vector Variables
23. Vector Functions of Scalar Argument
24. Some Notions Related to the Second Derivative
25. Osculating Circle
26. Evolute and Evolvent

Chapter VIII. Complex Numbers and Functions
§ 1. Complex Numbers

  1. Complex Plane
  2. Algebraic Operations on Complex Numbers
  3. Conjugate Complex Numbers
  4. Euler’s Formula
  5. Logarithms of Complex Numbers

§ 2. Complex Functions of a Real Argument
6. Definition and Properties
7*. Applications to Describing Oscillations

§ 3. The Concept of a Function of a Complex Variable
8. Factorization of a Polynomial
9*. Numerical Methods of Solving Algebraic Equations
10. Decomposition of a Rational Fraction into Partial Rational Fractions
11*. Some General Remarks on Functions of a Complex Variable

Chapter IX. Functions of Several Variables
§ 1. Functions of Two Variables

  1. Methods of Representing
  2. Domain of Definition
  3. Linear Function
  4. Continuity and Discontinuity
  5. Implicit Functions

§ 2. Functions of Arbitrary Number of Variables
6. Methods of Representing
7. Functions of Three Arguments
8. General Case
9. Concept of Field

§ 3. Partial Derivatives and Differentials of the First Order
10. Basic Definitions
11. Total Differential
12. Derivative of Composite Function
13. Derivative of Implicit Function

§ 4. Partial Derivatives and Differentials of Higher Orders
14. Definitions
15. Equality of Mixed Derivatives
16. Total Differentials of Higher Order

Chapter X. Solid Analytic Geometry
§ 1. Space Coordinates

  1. Coordinate Systems in Space
    2*. Degrees of Freedom

§ 2. Surfaces and Curves in Space
3. Surfaces in Space
4. Cylinders, Cones and Surfaces of Evolution
5. Curves in Space
6. Parametric Representation of Surfaces in Space. Parametric Representation of Functions of Several Variables

§ 3. Algebraic Surfaces of the First and the Second Orders
7. Algebraic Surfaces of the First Order
8. Ellipsoid
9. Hyperboloids
10. Paraboloids
11. General Review of Algebraic Surfaces of the Second Order

Chapter XI. Matrices and Their Applications
§ 1. Matrices

  1. Definitions
  2. Operations on Matrices
  3. Inverse Matrix
  4. Eigenvectors and Eigenvalues of a Matrix
  5. The Rank of a Matrix

§ 2. Linear Mappings
6. Linear Mapping and Its Matrix
7. Transformation of the Matrix of a Linear Mapping When the Basis Is Changed
8. The Matrix of a Mapping Relative to the Basis Consisting of Its Eigenvectors
9. Transforming Cartesian Basis
10. Symmetric Matrices

§ 3. Quadratic Forms
11. Quadratic Forms
12. Simplification of Equations of Second-Order Curves and Surfaces

§ 4. Non-Linear Mappings
13*. General Notions
14*. Non-Linear Mapping in the Small
15*. Functional Relation Between Functions

Chapter XII. Applications of Partial Derivatives
§ 1. Scalar Field

  1. Directional Derivative. Gradient
  2. Level Surfaces
  3. Implicit Functions of Two Independent Variables
  4. Plane Fields
  5. Envelope of One-Parameter Family of Curves

§ 2. Extremum of a Function of Several Variables
6. Taylor’s Formula for a Function of Several Variables
7. Extremum
8. The Method of Least Squares
9*. Curvature of Surfaces
10. Conditional Extremum
11. Extremum with Unilateral Constraints
12*. Numerical Solution of Systems of Equations

Chapter XIII. Indefinite Integral
§ 1. Elementary Methods of Integration

  1. Basic Definitions
  2. The Simplest Integrals
  3. The Simplest Properties of an Indefinite Integral
  4. Integration by Parts
  5. Integration by Change of Variable (by Substitution)

§ 2. Standard Methods of Integration
6. Integration of Rational Functions
7. Integration of Irrational Functions Involving Linear and Linear-Fractional Expressions
8. Integration of Irrational Expressions Containing Quadratic Trinomials
9. Integrals of Binomial Differentials
10. Integration of Functions Rationally Involving Trigonometric Functions
11. General Remarks

Chapter XIV. Definite Integral
§ 1. Definition and Basic Properties

  1. Examples Leading to the Concept of Definite Integral
  2. Basic Definition
  3. Relationship Between Definite Integral and Indefinite Integral
  4. Basic Properties of Definite Integral
  5. Integrating Inequalities

§ 2. Applications of Definite Integral
6. Two Schemes of Application
7. Differential Equations with Variables Separable
8. Computing Areas of Plane Geometric Figures
9. The Arc Length of a Curve
10. Computing Volumes of Solids
11. Computing Area of Surface of Revolution

§ 3. Numerical Integration
12. General Remarks
13. Formulas of Numerical Integration

§ 4. Improper Integrals
14. Integrals with Infinite Limits of Integration
15. Basic Properties of Integrals with Infinite Limits of Integration
16. Other Types of Improper Integral
17*. Gamma Function
18*. Beta Function
19*. Principal Value of Divergent Integral

§ 5. Integrals Dependent on Parameters
20*. Proper Integrals
21*. Improper Integrals

§ 6. Line Integrals
22. Line Integrals of the First Type
23. Line Integrals of the Second Type
24. Conditions for a Line Integral of the Second Type to Be Independent of the Path of Integration

§ 7. The Concept of Generalized Function
25*. Delta Function
26*. Application to Constructing Influence Function
27*. Other Generalized Functions

Chapter XV. Differential Equations
§ 1. General Notions

  1. Examples
  2. Basic Definitions

§ 2. First-Order Differential Equations
3. Geometric Meaning
4. Integrable Types of Equations
5*. Equation for Exponential Function
6. Integrating Exact Differential Equations
7*. Singular Points and Singular Solutions
8*. Equations Not Solved for the Derivative
9*. Method of Integration by Means of Differentiation

§ 3. Higher-Order Equations and Systems of Differential Equations
10. Higher-Order Differential Equations
11*. Connection Between Higher-Order Equations and Systems of First-Order Equations
12*. Geometric Interpretation of System of First-Order Equations
13*. First Integrals

§ 4. Linear Equations of General Form
14. Homogeneous Linear Equations
15. Non-Homogeneous Equations
16*. Boundary-Value Problems

§ 5. Linear Equations with Constant Coefficients
17. Homogeneous Equations
18. Non-Homogeneous Equations with Right-Hand Sides of Special Form
19*. Euler’s Equations
20*. Operators and the Operator Method of Solving Differential Equations

§ 6. Systems of Linear Equations
21. Systems of Linear Equations
22*. Applications to Testing Lyapunov Stability of Equilibrium State

§ 7. Approximate and Numerical Methods of Solving Differential Equations
23. Iterative Method
24*. Application of Taylor’s Series
25. Application of Power Series with Undetermined Coefficients
26*. Bessel’s Functions
27*. Small Parameter Method
28*. General Remarks on Dependence of Solutions on Parameters
29*. Methods of Minimizing Discrepancy
30*. Simplification Method
31. Euler’s Method
32. Runge-Kutta Method
33. Adams Method
34. Milne’s Method

Chapter XVI. Multiple Integrals
§ 1. Definition and Basic Properties of Multiple Integrals

  1. Some Examples Leading to the Notion of a Multiple Integral
  2. Definition of a Multiple Integral
  3. Basic Properties of Multiple Integrals
  4. Methods of Applying Multiple Integrals
  5. Geometric Meaning of an Integral over a Plane Region

§ 2. Two Types of Physical Quantities
6*. Basic Example. Mass and Its Density
7*. Quantities Distributed in Space

§ 3. Computing Multiple Integrals in Cartesian Coordinates
8. Integral over Rectangle
9. Integral over an Arbitrary Plane Region
10. Integral over an Arbitrary Surface
11. Integral over a Three-Dimensional Region

§ 4. Change of Variables in Multiple Integrals
12. Passing to Polar Coordinates in Plane
13. Passing to Cylindrical and Spherical Coordinates
14*. Curvilinear Coordinates in Plane

Chapter XVII. [Heading not present in the supplied contents]

§ 5. Fourier Transformation
32*. Fourier Transform
33*. Properties of Fourier Transforms
34*. Application to Oscillations of Infinite String

Chapter XVIII. Elements of the Theory of Probability
§ 1. Random Events and Their Probabilities

  1. Random Events
  2. Probability
  3. Basic Properties of Probabilities
  4. Theorem of Multiplication of Probabilities
  5. Theorem of Total Probability
    6*. Formulas for the Probability of Hypotheses
  6. Disregarding Low-Probability Events

§ 2. Random Variables
8. Definitions
9. Examples of Discrete Random Variables
10. Examples of Continuous Random Variables
11. Joint Distribution of Several Random Variables
12. Functions of Random Variables

§ 3. Numerical Characteristics of Random Variables
13. The Mean Value
14. Properties of the Mean Value
15. Variance
16*. Correlation
17. Characteristic Functions

§ 4. Applications of the Normal Law
18. The Normal Law as the Limiting One
19. Confidence Interval
20. Data Processing

Chapter XIX. Computers
§ 1. Two Classes of Computers

  1. Analogue Computers
  2. Digital Computers

§ 2. Programming
3. Number Systems
4. Representing Numbers in a Computer
5. Instructions
6. Examples of Programming

Appendix. Equations of Mathematical Physics
1*. Derivation of Some Equations
2*. Some Other Equations
3*. Initial and Boundary Conditions

§ 2. Method of Separation of Variables
4*. Basic Example
5*. Some Other Problems

Bibliography

Name Index

Subject Index

List of Symbols

 

 

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Engineering Thermodynamics by V.A. Kirillin; V.V. Sychev; A.E. Sheindlin

Although many Soviet and foreign textbooks in engineering thermodynamics already exist, the authors have decided to write a new textbook for university students in power engineering, heat physics, and applied physics departments. We have done so for the following reasons.

With improved instruction in thermodynamics in most higher educational institutions, the authors feel a more thorough presentation of basic problems is necessary. Of primary importance is an understanding of the fundamental concepts and methods of thermodynamics for analysing various physical phenomena.

Clearly, a modern course in engineering thermodynamics must reflect today’s and even tomorrow’s level of technology. Therefore, it is difficult to conceive of a modern textbook in thermodynamics which does not present the different methods of converting heat directly into electric power, modern methods of analysing the efficiency of the cycles of heating plants, the thermodynamics of dissociated and ionised gases, and other problems.

Since the authors consider it unjustified to include in courses of engineering thermodynamics problems relating to statistical physics and the molecular-kinetic theories of gases, we will limit ourselves to a short discussion of the statistical aspects of the second law of thermodynamics.

Although, as a rule, institutes of power engineering do not offer a special course in chemical thermodynamics, modern heat engineering involves many processes accompanied by chemical reactions, dissociation, and ionisation. The authors consider it necessary, therefore, to devote a special chapter to a short presentation of chemical thermodynamics to give the reader an idea of the methods applied in a thermodynamic description of chemical processes.

All numerical examples are given in the SI system (the unit to measure energy is the joule, and the unit to measure pressure is the pascal). As a general rule, along with their values in the SI system, the values of energy have also been indicated in calories (and pressure, in kgf/cm²).

The authors will be grateful for criticism and will take it into consideration in future work on the book.

 

Translated from the Russian by S. Semyonov

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Contents

Preface
Preface to the English edition

Introduction
Thermodynamics and its method
Properties of state
Concept of a thermodynamic process
Ideal gas Ideal gas laws
Concept of mixtures Mixtures of ideal gases
Concept of heat capacity

The first law of thermodynamics
Heat Joule’s experiment Equivalence of heat and work
Law of conservation and conversion of energy
Internal energy and external work
Mathematical statement of the first law of thermodynamics
Enthalpy
Mathematical statement of the first law of thermodynamics for processes of flow

The second law of thermodynamics
Cycles Concept of thermal efficiency Heat sources
Reversible and irreversible processes
Statements of the second law of thermodynamics
The Carnot cycle Carnot’s theorem
The thermodynamic temperature scale

Entropy
Change of entropy in irreversible processes
Combined mathematical statement of the first and second laws of thermodynamics
Entropy and thermodynamic probability
Reversibility and work

Differential equations of thermodynamics
Basic methods
Maxwell’s relations
Partial derivatives of internal energy and enthalpy
Heat capacities

Equilibrium in thermodynamic systems and phase changes
Homogeneous and heterogeneous thermodynamic systems
Thermodynamic equilibrium
Conditions of stability and equilibrium for an isolated homogeneous system
Conditions for phase equilibrium
Phase changes
The Clausius-Clapeyron equation
Phase stability
Phase changes at unequal phase pressures
Phase changes under curved surfaces

Thermodynamic properties of substances
Thermal and caloric properties of solids
Thermal and caloric properties of liquids
Andrews’ experiment The critical point Van der Waals’ equation
Thermal and caloric properties of real gases Equation of state for real gases
Thermodynamic properties of substances on the change-of-phase line Two-phase systems
Properties of substance at the critical point
Methods of calculating the entropy of substance
Thermodynamic diagrams of state for substances
Thermodynamic properties of substance in a metastable state

Basic thermodynamic processes
The isochoric process
The isobaric process
The isothermal process
The adiabatic process
Polytropic processes
Throttling The Joule-Thomson effect
Joule expansion (expansion into a vacuum)
Mixing
Compression processes

Fluid flow processes
Basic flow equations
Velocity of sound
Flow through convergent nozzles
Transonic range The Laval nozzle
Adiabatic flow with friction
General regularities of flow The influence inversion law
Adiabatic stagnation temperature

Methods to analyse the efficiency of thermopower plants
Cycle efficiency
Comparison methods for thermal efficiencies of reversible cycles
Method of efficiencies in the analysis of irreversible cycles
Entropy calculation method for the loss of availability in irreversible cycles
Exergy calculation method for availability losses

Gas power cycles
Cycles of reciprocating internal combustion engines
Gas-turbine cycles
Reaction-engine cycles

Vapour power cycles
The Carnot cycle
The Rankine cycle
Rankine cycle analysis allowing for irreversibilities

Reheat cycle

Regenerative cycle

Binary cycles

Thermification cycles

Cycles of direct-energy conversion systems

Thermoelectric generator cycle

The cycle of a thermionic converter

MHD-generator cycle

Refrigeration cycles

Reverse heat cycles and processes
Refrigeration installations

Air-compression refrigeration cycle

Vapour-compression refrigeration cycle

Steam-jet refrigeration cycle

Absorption refrigeration cycle

Thermoelectric refrigeration cycle

Heat pump
Principle of operation

Liquefaction of gases

Humid air

Basic concepts

I-d diagram for humid air

Fundamentals of chemical thermodynamics

Thermochemistry
Hess’s law
Kirchhoff’s equation

Chemical equilibrium and the second law of thermodynamics

Equilibrium constant and degree of dissociation

The Nernst heat theorem

Conclusion

Bibliography

Name index

Subject index

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Quimica Orgánica by V. M. Potapov; S. N. Tatarinchik

La química orgánica atraviesa un período de notable desarrollo caracterizado por el descubrimiento de nuevas sustancias con propiedades excepcionales y la creación de compuestos innovadores de aplicación práctica en diversas áreas. Este progreso se apoya en el uso de métodos modernos de investigación fundamentados en la física y en una profundización de las nociones teóricas. Sin embargo, esto plantea retos educativos, ya que es necesario condensar una gran cantidad de material en los planes de estudio. Los autores abogan por priorizar las leyes generales de la química orgánica, dejando en segundo plano el contenido puramente descriptivo, y basan su enfoque en la teoría de la estructura química de Bútlerov, complementada con una mejor comprensión de los enlaces químicos y las reacciones orgánicas. Este enfoque permite clasificar las reacciones de manera sistemática y facilitar su aprendizaje.

El libro sigue una clasificación basada en los grupos funcionales, que determinan el comportamiento químico de los compuestos orgánicos. Se abordan primero los hidrocarburos y luego sus derivados, incluyendo halogenados e hidroxílicos, destacando aquellos compuestos de relevancia práctica en la industria, agricultura y medicina. Para esta nueva edición, los autores han incorporado recomendaciones de instituciones académicas como las escuelas politécnicas de Moscú y Leningrado, ajustando el contenido al programa aprobado en 1974 para especialidades como química analítica y química de explotaciones petrolíferas. Finalmente, los autores invitan a los lectores a proporcionar observaciones críticas para mejorar la obra en futuras ediciones.

 

Traducido del ruso por Neiml Sosa

Todos los créditos a los cargadores originales.

Nota: La calidad del escaneo es promedio

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The Stranger by Titus Popovici

A Soviet era novel of the political awakening of a young Romanian intellectual in 1944.

Translated from the Romanian by Lazar Marinescu

Illustrations: P. Nazarie

Jacket: P. Vulcanescu

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Examples And Problems To The Course Of Unit Operations Of Chemical Engineering by K. F. Pavlov; P. G. Romankou; A. A. Noskov

The gaining of skill in solving practical engineering problems is very important for students of the course in unit operations. The Department of Unit Operations of Chemical Engineering at the Leningrad Technological Institute places great emphasis on this aspect, and the present book contains many examples and problems in the course that are the result of many years of instructional experience.

Great attention is devoted to the independent work of students, and problems are provided on all sections of the course:

Fundamentals of applied hydraulics
Pumps, fans, compressors
Hydromechanical separation methods
Hydrodynamics of a fluidised bed
Agitation in a liquid medium
Heat transfer in chemical apparatus
Evaporation, crystallisation
Mass transfer, absorption
Distillation and rectification
Extraction and leaching
Adsorption
Drying
Moderate and deep refrigeration
The basic formulas and equations needed for solving the problems are given at the beginning of each chapter. The appendices contain numerous reference tables and diagrams.

The present book, edited by Associate Member of the USSR Academy of Sciences, P. G. Romankov, is intended as a training aid for students of chemical engineering and related specialities in day, evening, and correspondence faculties. It will also be a useful aid in course and diploma designing.

About the Authors

Konstantin F. Pavlov (1895–1944)
Konstantin F. Pavlov was an outstanding specialist in the separation of natural and industrial gases. In 1934, he received his doctorate and the rank of professor. He headed the departments of Chemical Engineering of Inorganic Substances and General Chemical Engineering at the Leningrad Technological Institute, where, in 1936, he founded the first training laboratory in unit operations of chemical engineering in the country (now named after him).

He is the author of several training aids in chemical engineering and original research works (e.g., the rule of linearity of chemical engineering functions). During his final years, he worked in Moscow at the Institute of Physical Problems of the USSR Academy of Sciences.

Pyotr G. Romankov, D.Sc.
Professor Pyotr G. Romankov worked for many years as a chemical engineer and instructor at various chemical institutes. Since 1941, he has been the head of the Department of Unit Operations of Chemical Engineering at the Leningrad Technological Institute. Together with his pupils and collaborators, he has published over 250 scientific works, including several monographs on the theory and application of hydromechanical, heat, and mass-exchange processes of chemical engineering.

In 1964, Pyotr Romankov was elected an associate member of the USSR Academy of Sciences. He is an Honoured Scientist of the RSFSR and has received numerous government awards. He is also a Doctor honoris causa of several foreign higher educational establishments.

Anatoli A. Noskov (1904–1977)
Anatoli A. Noskov worked for many years as an engineer in gas separation under the guidance of Prof. Konstantin Pavlov. He was later invited to work at the Department of Unit Operations of Chemical Engineering at the Leningrad Technological Institute, where he advanced from lecturer to professor.

Anatoli Noskov is well known for his contributions to improving rectification processes and methods for calculating standard operations of chemical engineering.

Edited by P. G. Romankov
Associate Member, USSR Academy of Sciences

Translated from the Russian by G. Leib

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Contents

CONTENTS
Preface
Introductory Methodical Instructions
Chapter 1. FUNDAMENTALS OF APPLIED HYDRAULICS
Fundamental Relationships and Formulas for Calculations
Examples
Problems
Symbols
Chapter 2. PUMPS, FANS, COMPRESSORS
Fundamental Relationships and Formulas for Calculations
Examples
Problems
Symbols
Chapter 3. HYDROMECHANICAL SEPARATION METHODS. HYDRODYNAMICS OF A FLUIDIZED BED. AGITATION IN A LIQUID MEDIUM
Fundamental Relationships and Formulas for Calculations
Settling
Filtration
Centrifugal Separation
Hydrodynamics of a Fluidized Bed
Agitation in a Liquid Medium
Examples
Settling
Filtration
Centrifugal Filtration
Fluidized Bed
Agitation in a Liquid Medium
Problems
Example of Calculating and Selecting a Multi-Tube Cyclone Separator
Example of Calculating and Selecting a Foam Gas Washer for Purifying a Gas of Dust
Example of Calculating and Selecting a Rotary Vacuum Filter
Symbols
Chapter 4. HEAT TRANSFER IN A CHEMICAL APPARATUS
Fundamental Relationships and Formulas for Calculations
Heat Conduction
Heat Transfer
Overall Heat Transfer in Surface Heat Exchangers
Overall Heat Transfer in Direct Contact of Streams
Approximate Values of Individual and Overall Heat Transfer Coefficients
Examples
Problems
Examples of Calculating and Selecting Heat Exchangers
Symbols
Chapter 5. EVAPORATION. CRYSTALLIZATION
Fundamental Relationships and Formulas for Calculations
Examples
Problems
Example of Calculating and Selecting a Triple-Effect Evaporator
Symbols
Chapter 6. MASS TRANSFER. ABSORPTION
Fundamental Relationships and Formulas for Calculations
Examples
Problems
Symbols
Chapter 7. DISTILLATION AND RECTIFICATION
Fundamental Relationships and Formulas for Calculations
Examples
Problems
Example of Calculating and Selecting a Plate Rectification Column
Symbols
Chapter 8. EXTRACTION AND LEACHING
Fundamental Relationships and Formulas for Calculations
Examples
Problems
Symbols
Chapter 9. ADSORPTION
Fundamental Relationships and Formulas for Calculations
Examples
Problems
Symbols
Chapter 10. DRYING
Fundamental Relationships and Formulas for Calculations
Examples
Problems
Example of Calculating and Selecting a Fluidized-Bed Dryer for Drying Potassium Chloride
Example of Calculating and Selecting a Drum Dryer
Symbols
Chapter 11. MODERATE AND DEEP REFRIGERATION
Fundamental Relationships and Formulas for Calculations
Examples
Problems
Symbols
Answers to Problems
Bibliography
Appendices
Guide to Tables and Diagrams in Appendices

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Fundamentals Of Crystal Physics by Yu.I. Sirotin; M.P. Shaskolskaya

Over the past 15-20 years, experimental crystal physics has expanded beyond research laboratories and into practical applications in fields like quantum electronics, optics, semiconductor production, and piezotechnology. These advancements have highlighted the need for comprehensive textbooks on crystal physics. This book aims to fill that gap, offering a more detailed work to complement Nye’s 1967 textbook. It focuses on combining general physical principles with the symmetry approach characteristic of the Soviet crystal physics school founded by A.V. Shubnikov. The content is based on lectures and courses delivered at the Moscow Institute of Steel and Alloys and Moscow State University.

The book focuses on the anisotropy of crystal properties, particularly in areas such as diffusion, dielectric permittivity, magnetostriction, and piezooptical effects. It includes illustrations like representation surfaces and stereographic projections to explain the anisotropy of physical properties. The authors also provide a novel description of phase transitions with a double change of symmetry, illustrating how crystal properties change during phase transitions. The appendices include reference data, enhancing the book’s practical utility.

Translated from the Russian by Valentina Snigirevskaya.
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Contents

 

Preface to the Second Russian Edition 9
Excerpts from the Preface to the First Russian Edition 10
List of Notation 13

Chapter I. Basic Information on Crystallography 17

Crystal Structure and Space Lattice 17

Crystallographic Projections 23

Simple Finite Elements of the Symmetry of Crystals 27

Crystallographic Categories and Systems 42

Point Groups of Crystal Symmetry (Symmetry Classes) 47

Derivation and Description of 32 Classes of Crystal Symmetry (32 Point Groups of Symmetry) 55

Limit Groups of Symmetry (Curie Groups) 68

Symmetry of Crystal Structure 71

Combinations of the Symmetry Elements of Structures. Bravais Lattices. Generation of New Symmetry Elements 74

230 Space Groups of Symmetry 84

Mutual Vectors Basis and Reciprocal Lattice 88

Indexing of Directions and Planes in Crystals 92

Transformation of Indices with a Change of the System of Coordinates 101

Symmetrically Equivalent Sets of Planes and Directions. Simple Crystal Forms 114

Some Problems of Geometric Crystallography 125

Chapter II. Coordinate Systems, Vectors and Tensors 134

16. Cartesian Coordinate Systems 134
17. Orthogonal Transformations 137
18. Second-Rank Tensors 144
19. Eigenvectors and Eigenvalues of a Symmetric Second-Rank Tensors 147
20. Small Changes of a Symmetric Second-Rank Tensor 152
21. Normal and Tangential Components of a Second-Rank Symmetric Tensor 155
22. External Symmetry and Representation of Vectors and Second-Rank Symmetric Tensors 159
23. Axial Vectors 165

Chapter III. Introduction to Crystal Physics. Electrical and Thermal Properties of Crystals 174
24. Anisotropic Continuous Media 174
25. The Symmetry Principle in Crystal Physics 182
26. Fundamental Equations of Electrostatics of Crystals 188
27. Symmetry of the Dielectric Properties of Crystals 191
28. Crystals in a Uniform Electric Field 196
29. The Field in a Spherical Gap in an Anisotropic Medium 201
30. Fields of a Point Charge and a Dipole in an Anisotropic Medium 204
31. Pyroelectrics 207
32. Direct Electric Current in Crystals 210
33. Thermal Conductivity of Crystals 212

Chapter IV. Optical Properties of Crystals 216
34. Electromagnetic Waves in Transparent Crystals 216
35. Optical Indicatrix 220
36. Waves and Rays. Principle of Duality. Fresnel’s Ellipsoid 227
37. Solution of the Problem of Light Propagation in a Crystal in an Arbitrary System of Coordinates 232
38. Fresnel’s Equation. Wave and Ray Surfaces 236
39. Interconnection Between the Optical Surfaces in Crystals. Conical Refraction 240
40. Observation of the Optical Anisotropy of Crystals in Polarized Light 245

Chapter V. Symmetry of Higher-Rank Tensors 253
41. Tensors and Pseudotensors of Higher Ranks 253
42. Internal Symmetry of Tensors and Duality Relations 257
43. Non-Coordinate Notation of Tensors. Invariant Differential Operations on Tensors 263
44. External Symmetry and Representation of Tensors and Pseudotensors 266
45. Method of Direct Verification 275
46. Cyclic Coordinates. Hermann’s Theorem 281
47. Application of the Theory of Group Representation to the Problems of Tensor Symmetry 287
48. The Isotropic and Gyrotropic Tensors 301

Chapter VI. Elasticity of Crystals 308
49. Small Strains of a Continuous Medium 308
50. Stress Tensor 314
51. Generalized Hooke’s Law 319
52. Symmetry of the Elastic Properties of Crystals 324
53. Simple States of Stress 330
54. Bending and Twisting of Crystals 339
55. Temperature Stresses in Crystals 350
56. Elastic Waves in Crystals 358

Chapter VII. Thermodynamics of Crystals
57. Internal Energy and Thermodynamic Potential of a Crystal 380
58. Piezoelectric Effect and Its Symmetry 386
59. Simultaneous Solution of the Equations of the Electro- and Elastostatics of Crystals 396
60. Invariant and Non-Invariant Thermodynamic Potentials and Their Matrices 406
61. Dependence of Thermodynamic Coefficients on Conditions of Measurement 411
62. Elastic Waves in Piezoelectric Crystals 416
63. Thermodynamic Inequalities 419
64. Alterations of Crystal Symmetry in Phase Transitions of the Second Kind 423
65. Changes of the Physical Properties of Crystals Under Phase Transitions of the Second Kind 430
66. Mathematical Methods of the Theory of Phase Transitions 445

Chapter VIII. Magnetic Symmetry in Crystal Physics
67. Time Reversal and Antisymmetry 456
68. Point Groups of Magnetic Symmetry 460
69. Space Groups of Magnetic Symmetry—Shubnikov’s Groups 466
70. Magnetic Symmetry of Crystals 470
71. Geometric Realization of the Expanded Orthogonal Group 476
72. Tensors Defined on an Expanded Orthogonal Group 479
73. Piezomagnetic and Magnetoelectric Effects 485

Chapter IX. Effects of the Higher Orders
74. Thermodynamic Consideration of Non-Linear Effects 488
75. Piezoresistive Effect 491
76. Onsager Reciprocal Relations and Thermogalvanomagnetic Effects 493
77. Electrooptical and Piezooptical Effects 503
78. Artificial Optical Anisotropy of Crystals 508
79. Non-Linear Polarization in Case of Propagation of Electromagnetic Intense Waves 515
80. Generation of Light Harmonics. Directions of Synchronism 519
81. Optical Activity of Crystals 525
82. Artificial Optical Activity 540
83. Acoustic Activity of Crystals 545

Chapter X. Some General Problems of Crystal Physics
84. Extreme-Value Problems of Crystal Physics 551
85. The Problem of Comparing Tensor Properties of Crystals 535
86. The Problem of Choosing Standard Crystallographic and Crystal-Physical Systems of Coordinates 561
87. Functional Relations in Crystal Physics 556

Appendices
A. Crystallographic and Crystal-Physical Systems of Coordinates 581
B. Bravais Lattices and Crystallographic Matrices 581
C. Properties of Directions in Crystals 590
D. Analytical Proof of Theorems on the Multiplication of Symmetry Operations 597
E. Tensors Invariant with Respect to Crystallographic and Limit Groups 627
F. Contracted Notation of Tensors 627

References 637
Index 646

 

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Steam Power Plant Piping Design by B. Rudomino; Yu. Remzhin

In the last decade, Soviet heat-power engineering has made significant advancements, including increased power plant capacities and improvements in thermodynamic cycles through intermediate superheating and higher steam parameters. These changes have simplified piping layouts in some aspects, but also made them more complex due to the need for superheating. The use of higher steam parameters has necessitated the use of stronger steels and thicker-walled pipes, which in turn requires better piping design methods. Current strength calculations for pipelines are governed by standards like “The Standard Procedures to Calculate Steam Boiler Elements for Strength” and industry-specific standards, ensuring mass production of piping elements while focusing on general strength principles.

The advent of digital computers has greatly enhanced piping design, enabling complex calculations for self-compensating pipelines and systems with movable inflection points and multiple anchor points. This book outlines the general theory of computer-aided pipeline design and presents a simpler calculation procedure with adequate accuracy. It emphasizes the importance of considering the deformation of bent ovalled elbows under internal pressure. It also introduces methods for calculating thermal expansion compensation using bellows-type expansion joints, as well as hydrodynamic calculations for pipelines with large pressure drops. The book is primarily aimed at engineers designing thermal power stations and can serve as a textbook for students in the field.

Translated from the Russian by Prem Kumar Dang
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Foreword 7
Chapter One
Piping Layout and Design 9
1.1. Piping Project Design 9
1.2. Layout and Design 12
1.3. Drainage of Pipelines 20
1.4. Pipeline Supports 24
1.5. Application of Pipe Fittings 35
Chapter Two
Hydrodynamic Calculations and Selection of Pipe Diameter 40
2.1. General Information and Formulas 40
2.2. Resistance Coefficients 51
2.3. Hydrodynamic Calculations of Pipelines for Small Specific Volume Changes 59
2.4. Hydrodynamic Calculations of Pipes with Large Steam Specific Volume Variations 66
2.5. Hydrodynamic Calculations of Boiling Water and High-Pressure Saturated Steam Pipelines 88
2.6. Selection of the Most Rational Pipe Size 106
Chapter Three
Pipeline Structural Calculations 117
3.1. General 117
3.2. Basic Properties of Steels Used for Power Station Pipelines 121
3.3. Wall Thickness Calculations 128
3.4. Calculation for Combined Action of Internal Pressure and Additional External Loads 132
3.5. Self-Elongation of Pipelines 138
3.6. Check Calculation of Stresses Caused by Compensating for Thermal Elongations 143
3.7. Flexure in Curved Pipes and Equivalent Stress Ranges 149
3.8. Check Calculation of Elbows for Cyclic Stress Ranges 161
3.9. Hydrodynamic Forces in Pipelines 172
Chapter Four
Pipeline Thermal Elongation Compensation and Its Calculation 176
4.1. Methods of Compensating Thermal Elongations 176
4.2. Self-Compensation Problem and Methods of Its Solution 177
4.3. Coordinate System and Determination of Displacements to Be Compensated 180
4.4. General Theory of Pipeline Calculation for Self-Compensation 186
4.5. Determination of Bending Moments Due to Weight Load 196
4.6. Methods of Calculating Pipelines for Self-Compensation 200
4.7. Bellows-Type Expansion Joints and Their Use as Axial Expansion Joints 215
4.8. Compensation of Pipelines Through the Use of Bellows-Type Expansion Joints as Elastic Hinges 222
4.9. Use of Electronic Digital Computing Machines for Calculating Self-Compensation of Pipelines 230
4.10. Criterion for Calculating the Compensating Capacity of Pipelines 234
Appendices 237
Index 269

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Examples And Problems In Chemical Thermodynamics by M.Kh. Karapetyants

The present textbook is a study aid to the course in chemical thermodynamics.

The examples and problems contained in it cover the most essential and characteristic sections of the course, which should assist students in mastering the elementary methods of both general thermodynamic calculations and special calculations connected with separate processes of chemical technology.

The topics of the examples and problems mainly reflect questions concerning the technology of inorganic production processes and the chemical processing and refining of fuel. In this connection, the main attention has been devoted to gaseous systems.

Each chapter of the book begins with a brief theoretical introduction containing the equations and formulas needed for calculations. This is followed by examples with detailed solutions and problems.

The examples contain all the data necessary for calculations and can be used for independent solution. In compiling the book, the author tried to avoid identical examples and problems (using the same formulas and quantities, but describing different objects).

For a greater approximation to practical calculations, the book acquaints students with approximate methods of computation, graphical methods of calculation, and with some semi-empirical and empirical laws. The results of the calculations, when possible, are compared with experimental data or with calculations by other methods, which makes it possible to assess the accuracy of different methods and the limits of their application.

A considerable part of the examples and problems have been drawn up according to the published works of Soviet investigators. The experimental data are also taken from reference books and monographs. Some problems have been taken from different textbooks.

Translated from the Russian by G. Leib

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Preface 5
List of Symbols 9
Chapter One. The First Law of Thermodynamics 11
Chapter Two. Heats, Heat Capacity and Enthalpy 19
2.1. Hess’s Law 19
2.2. Thermochemical Laws 26
2.3. Heat Capacity and Enthalpy 31
2.4. Theoretical Temperature of Combustion 45
2.5. Influence of Temperature on Heat Reaction 49
Chapter Three. The Second Law of Thermodynamics 58
3.1. Entropy 58
3.2. Thermodynamic Potentials 76
Chapter Four. Real Gases 82
4.1. Pressure-Volume-Temperature-Composition Relationships 82
4.2. Fugacity 94
4.3. Heat Capacity 100
4.4. Enthalpy 104
4.5. Joule-Thomson Effect 109
Chapter Five. One-Component Heterogeneous Systems 114
5.1. Clapeyron-Clausius Equation 114
5.2. Methods for Comparative Calculation of the Temperature Dependence of Saturated Vapour Pressure 127
5.3. Critical Parameters 132
5.4. Heat Capacities of Coexisting Phases and Heats of Phase Transitions 137
Chapter Six. Generalized Methods of Calculation 145
6.1. Gases 145
6.2. Liquid-Vapour Equilibrium 156
Chapter Seven. Solubility 160
7.1. Influence of Temperature 160
7.2. Influence of Pressure 173
7.3. Mutual Solubility of Liquids 183
Chapter Eight. Vapour Pressure of Solutions 191
8.1. Completely Miscible Liquids 191
8.2. Incompletely Miscible and Immiscible Liquids 200
Chapter Nine. Equilibrium Constant and Change in Standard Gibbs Energy 209
9.1. Calculation of K and AG° According to Equilibrium Data 209
9.2. Calculation of K and AG° According to Thermal Data 225
Chapter Ten. Equilibrium Transition 243
10.1. Calculation of Equilibrium Transition 243
10.2. Influence of Various Factors on the Extent of a Reaction 252
10.3. Calculating the Equilibrium of Complex Processes 261
Answers to Problems 271
Chapter One 271
Chapter Two 271
Chapter Three 273
Chapter Four 275
Chapter Five 276
Chapter Six 279
Chapter Seven 280
Chapter Eight 282
Chapter Nine 283
Chapter Ten 285
Appendices 288

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Chemical Thermodynamics by M.Kh. Karapetyants

The book is primarily aimed at students in higher education specialising in chemistry, particularly future engineers. The author has avoided unnecessary abstraction and overly complex mathematics to ensure the material remains practical and accessible, while still providing a solid theoretical foundation. The content includes approximate laws that allow for quick, practical problem-solving, even when precise values are unavailable. The author integrates empirical thermodynamics with the periodic table to make thermodynamic concepts more comprehensible, particularly entropy, which students often find difficult to grasp.

The book also addresses the importance of connecting thermodynamics with other branches of chemistry, such as general and inorganic chemistry, to enhance students’ understanding for later courses. The primary focus is on the thermodynamics of gaseous systems, with less emphasis on solutions and electrolytes. Numerous examples, mainly related to inorganic substances and chemical processing, help students apply theory to practical problems, with calculations that can be compared to experimental data. The book also includes many tables and figures derived from various sources to support these applications.

 

Translated from the Russian by G. Leib

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Contents

List of Tables 11
Preface 13
Chapter 1. INTRODUCTION 15
1.1. The Subject and Method of Thermodynamics 15
1.2. Basic Concepts and Definitions 17
1.2.1. Systems and Their Classification 17
1.2.2. Thermodynamic Parameters 18
1.2.3. Work and Heat 22
1.2.4. Reversible and Irreversible Processes 23
1.2.5. Mathematical Relations Between the Parameters of State 28
1.3. Terms and Symbols 33
Chapter 2. THE FIRST LAW OF THERMODYNAMICS 35
2.1. Content of the First Law 35
2.1.1. Cyclic Processes 35
2.1.2. Non-Cyclic Processes. Internal Energy 36
2.2. Enthalpy 41
Chapter 3. HEAT EFFECTS AND HEAT CAPACITIES 45
3.1. Hess’s Law 45
3.2. Standard Heat Effects 49
3.3. Some Methods of Calculating Heat Effects 53
3.3.1. Heats of Formation 53
3.3.2. Heats of Combustion 57
3.3.3. Comparative Calculation of Heat Effects 58
3.4. Heat Capacity 58
3.4.1. Heat Capacity in Different Processes 58
3.4.2. Temperature Dependence of Heat Capacity 61
3.4.3. Certain Laws 71
3.5. Temperature Dependence of Heat Effect 73
3.5.1. Kirchhoff Equation 73
3.5.2. Equation AH = <p(T) in Its Final Form 77
3.5.3. Heat Balance 84
Chapter 4. THE SECOND LAW OF THERMODYNAMICS 87
4.1. Content of the Second Law 87
4.1.1. The Carnot Cycle 87
4.1.2. Thermodynamic Temperature Scale 91
4.1.3. Impossibility of a Perpetual Motion Machine 92
4.2. Entropy 94
4.2.1. Change in Entropy in Reversible Processes 95
4.2.2. Change in Entropy in Irreversible Processes 97
4.2.3. Change in Entropy as a Criterion of the Equilibrium and Spontaneity of Processes 98
4.2.4. Relation Between Entropy and Other Thermodynamic Parameters and Some Relationships Between Derived Functions 102
4.3. Substantiation of the Second Law 106
4.3.1. Thermodynamic Probability of a State 106
4.3.2. Phase Space 106
4.3.3. Relationship Between Entropy and Thermodynamic Probability 108
4.3.4. Fluctuations 110
4.3.5. The Invalidity of the “Theory of Heat Death” of the Universe 112
Chapter 5. THERMODYNAMIC AND CHEMICAL POTENTIALS. THE GENERAL CONDITIONS OF EQUILIBRIUM 114
5.1. Thermodynamic Potentials 114
5.1.1. Change in Thermodynamic Potential as a Criterion of the Equilibrium and Spontaneous Nature of a Process 119
5.1.2. Various Thermodynamic Relationships 121
5.2. Characteristic Functions 123
5.3. Chemical Potential 128
5.4. General Conditions of Equilibrium 131
5.4.1. Stable and Unstable Equilibria 132
5.4.2. Equilibrium Coexistence of Phases. The Gibbs Phase Rule 134
5.4.3. Principle of Displacement of Equilibrium 139
Chapter 6. ONE-COMPONENT HOMOGENEOUS SYSTEMS 141
6.1. Ideal Gas 141
6.2. Equations of State of a Real Gas 150
6.3. Fugacity 159
6.3.1. Standard State 160
6.3.2. Temperature Dependence of Fugacity 162
6.3.3. Methods of Calculating Fugacity 163
6.4. Throttling 168
6.5. Calculation of Properties of Gases According to Experimental Data 175
6.5.1. Calculations Using the Relationships p-V-T and Cp = q>(T) 175
6.5.2. Calculations Using the Relationships Cp = <p(p, T) or H = q(p, T) and VT> = 9 (p) 184
6.5.3. Calculations Using (ij and C9 185
6.5.4. Influence of Pressure on the Heat Effect of a Reaction 185
6.6. A Generalized Method of Calculating Selected Properties of Gases and Liquids at Pressures above Atmospheric 186
6.6.1. Gases 186
6.6.2. Liquids 199
Chapter 7. ONE-COMPONENT HETEROGENEOUS SYSTEMS 205
7.1. Relationship Between Temperature and Pressure with Coexisting Phases 205
7.1.1. Clapeyron-Clausius Equation 205
7.1.2. Approximate Relationships 209
7.2. Methods for the Comparative Calculation of the Temperature Dependence of the Saturated Vapour Pressure 214
7.2.1. Straight Line Method 215
7.2.2. Method of Comparing Boiling Points of Given and Standard Substances at Equal Vapour Pressures 216
7.2.3. Method of Comparing Vapour Pressures of Various Substances at Equal Boiling Points 218
7.2.4. Method of Comparing Vapour Pressures of Various Substances at Equal Reduced Boiling Points 220
7.3. Critical State 221
7.4. Heat Capacities of Coexisting Phases and Heats of Phase Transitions 227
7.4.1. Heat Capacities of Coexisting Phases 227
7.4.2. Heats of Phase Transitions 232
7.5. Influence of Total Pressure on Saturated Vapour Pressure 244
7.6. Influence of Surface Curvature on Saturated Vapour Pressure 247
7.7. Second-Order Phase Transitions 249
Chapter 8. SOLUTIONS 251
8.1. Fundamental Concepts and Definitions 251
8.2. Partial Molar Quantities 255
8.2.1. Basic Equations 257
8.2.2. Methods of Calculation 260
8.3. Heat Capacities and Enthalpies of Solutions 264
8.3.1. Partial Molar Heat Capacities 264
8.3.2. Partial Molar Enthalpies 265
8.4. Ideal Solutions 272
8.5. Infinitely Dilute Solutions 278
8.5.1. Partial Molar Quantities 279
8.5.2. Henry’s Law 281
Chapter 9. BINARY SOLUTION-PURE COMPONENT EQUILIBRIUM 285
9.1. Relationship Between Temperature and Concentration 285
9.1.1. Solution-Solid Component Equilibrium 287
9.1.2. Analysis of Solubility Diagrams 292
9.1.3. Solution-Gas Equilibrium 304
9.2. Relationship Between Pressure and Concentration 305
9.2.1. Solution-Solid Component Equilibrium 306
9.2.2. Solution-Gas Equilibrium 307
9.3. Gas Mixture-Pure Component Equilibrium 317
9.4. Influence of Dispersion on Solubility 318
Chapter 10. SOLUTION-SOLUTION EQUILIBRIUM IN BINARY MIXTURES 319
10.1. Liquid-Gas Equilibrium for Completely Miscible Liquids at Low Pressures 319
10.1.1. Ideal Solution-Mixture of Ideal Gases 319
10.1.2. Non-Ideal Solution-Mixture of Ideal Gases 322
10.1.3. Separation of Solution Components 332
10.2. Liquid-Gas Equilibrium for Completely Miscible Liquids at High Pressures 334
10.2.1. Critical Phenomena 341
10.3. Equilibrium in Systems with Incompletely Miscible Liquids 349
10.3.1. Liquid-Gas Equilibrium 349
10.3.2. Liquid-Liquid Equilibrium 351
10.3.3. Gas-Gas Equilibrium 352
10.4. Liquid-Gas Equilibrium for Immiscible Liquids 355
Chapter 11. EQUILIBRIUM IN THREE- AND FOUR-COMPONENT SYSTEMS 359
11.1. Depicting Composition 359
11.1.1. Three-Component Systems 359
11.1.2. Four-Component Systems 361
11.2. Liquid-Solid Equilibrium in Three-Component Systems 362
11.2.1. Substances Forming No Compounds 362
11.2.2. Substances Forming Compounds 366
11.2.3. Isotherms of Aqueous Solutions of Two Common-Ion Salts 367
11.3. Mutual Solubility of Three Liquids 385
11.4. Liquid-Gas Equilibrium in Ternary Systems 391
11.4.1. Isotherm 391
11.4.2. Is

obaric Systems 399
Chapter 12. THE PRINCIPLE OF MAXIMUM ENTROPY 405
12.1. Entropy as a Thermodynamic Function 405
12.2. Method of Maximum Entropy 410
12.3. Application of the Maximum Entropy Principle in Thermodynamics 414
Chapter 13. MODERN CONCEPTS OF THERMODYNAMICS 419
13.1. Thermodynamic Models 419
13.2. Relations with Other Areas of Science 421
13.3. Role of Thermodynamics in Physical Chemistry 424
13.4. Applications of Thermodynamics in Industry 427
13.5. Advanced Topics in Thermodynamics 430

Chapter 14. EQUILIBRIUM TRANSFORMATION 518

14.1. Direction of a Process 518

14.2. Calculation of Equilibrium Transformation 527

14.2.1. Reactions in the Gaseous Phase 528

14.2.2. Reactions in Solutions 531

14.2.3. Heterogeneous Reactions 533

14.2.4. Electrochemical Reactions 537

14.3. Influence of Various Factors on the Extent of a Reaction 541

14.3.1. Temperature 541

14.3.2. Pressure 545

14.3.3. Presence of an Inert Gas 548

14.3.4. Ratio of Reactants 549

14.3.5. Change in Surface Area 550

14.3.6. Kind of Reaction 552

14.4. Equilibrium in Complex Chemical Systems 553

14.5. Sources of Errors in Calculating Equilibrium 562

14.5.1. Errors Due to Inaccuracy of Experimental Data 562

14.5.2. Errors Connected with the Processing of Experimental Data 564

14.6. Theoretical and Practical Extents of a Reaction 566

 

Chapter 15. FUNDAMENTALS OF QUANTUM STATISTICAL CALCULATIONS OF THERMODYNAMIC FUNCTIONS AND CHEMICAL EQUILIBRIUM FROM SPECTROSCOPIC DATA 568

15.1. Introduction 568

15.2. Thermodynamic Properties of Gases Due to Translational Degrees of Freedom 572

15.3. Thermodynamic Properties of Gases Due to Intramolecular Degrees of Freedom 575

15.3.1. Rotational Partition Function 577

15.3.2. Vibrational Partition Function 583

15.3.3. Partition Function for Electronic Excitation 587

15.3.4. Nuclear Spin 588

15.3.5. Effect of Isotopic Composition 589

15.3.6. Group of Properties 589

15.4. Calculation of Chemical Equilibrium 592

APPENDICES 599

List of Symbols 599

Heat Capacities, Standard Enthalpies and Gibbs Energies of

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